Performance Evaluation and Biodegradation Study of Polyvinyl Chloride Films with Castor Oil-based Plasticizer

In the present study, a renewable resource-based plasticizer was synthesized by the lipase-catalyzed esterification reaction of furfuryl alcohol (FA) and castor oil fatty acid (COFA). The resultant ester (FA-COFA ester) was used as secondary plasticizers to the polyvinyl chloride (PVC) films. The PVC films were formulated using the combination of a conventional plasticizer di-butyl phthalate (DBP) and FA-COFA ester as a secondary plasticizer at different concentrations. Films were characterized by X-ray diffraction analysis, scanning electron microscopy, thermal analysis, mechanical performance, and migration stability. A biodegradability study of the PVC films showed increased degradability with increasing concentration of the FA-COFA ester in the PVC film. The study showed that ester of FA and COFA could be a substitute of DBP by as much as 80% of the total plasticizer with improved elongation and tensile properties, and such a kind of sustainable resource-based PVC blend films could be used as a good packaging material with biodegradable property.     

The Effect of Addition of High-Melting Monoacylglycerol and Candelilla Wax on Pea and Faba Bean Protein Foam-Templated Oleogelation

Use of oleogels prepared from hydrocolloids has recently gained considerable attention as an alternative for trans and saturated fats. Lately, pulse proteins such as faba bean protein and pea protein have been successfully used to prepare oleogels using a foam-templated approach. Although the pulse proteins are healthy oleogelators, high oil loss and low quality of cake baked using pulse protein-stabilized oleogels due to its poor rheological properties challenged its use. The present study explored whether the addition of small amount of high-melting monoglyceride (MAG) or candelilla wax (CW) can be used to improve the oil binding capacity, rheological properties, and baking qualities of pulse protein-stabilized oleogels composed of 5% faba bean or pea protein concentrate with 0.25% xanthan gum foams. Different concentrations (0.5–3%) of MAG or CW were dissolved in canola oil at 80 °C, followed by addition into the freeze-dried protein-polysaccharide foams (pH 7) and quickly transferred to a refrigerator to facilitate the formation of oleogels. The crystallized additives were found to be reinforcing the protein foam network in the oleogels. With increase in concentration of CW and MAG, the oil binding capacity, firmness, cohesiveness, and storage moduli of the oleogels were increased. Oleogels with and without MAG or CW were then characterized and tested for their performance as a shortening replacer in model baked cakes. Findings showed improved textural properties of cake upon addition of MAG in the foam-templated oleogels, however, compared to the shortening, negative effect on cake hardness and chewiness was still observed with the oleogels.     

Isolation and identification of phosphate‐solubilizing microorganisms and distribution of orthophosphate in different seasons from sewage‐fed East Kolkata Wetland

This study focused on isolation and identification of possible phosphate‐solubilizing bacteria (PSB ) from the sewage‐fed East Kolkata Wetland (EKWL ), a prospective water resource for pisciculture. In addition, different limnological parameters have been correlated with orthophosphate and seasonal variations. PSB have been isolated in Pikovskaya medium and identified morphologically and biochemically and finally analysed by 16S rDNA gene sequence. Limnological studies involving temperature (potentiometric), pH (potentiometric), dissolved oxygen (iodometric), ammonia‐nitrogen (spectrophotometric) and orthophosphate (spectrophotometric) concentrations were conducted. The results of this study established the presence of Bacillus megaterium , a potential PSB in EKWL . The activity of B. megaterium is also supported by the seasonal orthophosphate variations. The changes in concentration of other limnological parameters were also prominent. The water quality parameters of temperature (r  = 0.886), dissolved oxygen (r  = 0.729) and ammonia‐nitrogen (r  = 0.396) concentrations exhibited a positive correlation with orthophosphate and a negative correlation with pH (r  = ?0.699). The B. megaterium obtained in this study, exhibited a significant alteration in regard to orthophosphate content and relationships with other factors. Further experiment on the soluble phosphorus solubilization potential of B. megaterium revealed the biological availability of phosphorus was increased by threefold after 120 hr of incubation, with the decreasing pH value, although the phytase activity was 0.419 U/ml. PSB have a vital function in plant nutrition in supplying phosphate, essential nutrients and its uptake results in appropriate functioning and metabolism of different aquatic plants and organisms. PSB are competent biofertilizer to amplify aquaculture production for sustainable development.     

Offshore manufacturing contract design based on transfer price considering green tax: a bilevel programming approach

The problem of designing offshore manufacturing contract resulting in optimal transfer price is troubling multinational companies over the past few years. This paper proposes designing offshore manufacturing contracts based on the transfer price in the form of bilevel programming problems after considering green tax. In these contract designs, a firm in a developed country sells a single product in its market. The same product is simultaneously being manufactured by another firm in a developing country with lower manufacturing cost. After anticipating the consumer demand, the seller places an order, based on which the manufacturer manufactures the ordered quantity, and offers a transfer price which in turn maximises its net profit after paying green tax to its government. While setting the transfer price, the manufacturer considers the manufacturing cost, the export duty payable to its government and the cost of shipping the product to the developed country. After buying the product from the manufacturer at the transfer price, the seller then sets the retail price which maximises its net profit after paying the import duty to its government; the retail price, however, must not be more than the maximum retail price applicable to the market. Thus, offshore manufacturing contract results in optimal after-tax profits for both the firms. An experimental study has been carried out to discuss the practical aspects of the results developed, where a US firm is offshoring its manufacturing activity to a Chinese firm in order to draw maximum profit.     

Self-Assembly and Neurotoxicity of β-Amyloid (21–40) Peptide Fragment: The Regulatory Role of GxxxG Motifs

The three GxxxG repeating motifs from the C-terminal region of β-amyloid (Aβ) peptide play a significant role in regulating the aggregation kinetics of the peptide. Mutation of these glycine residues to leucine greatly accelerates the fibrillation process but generates a varied toxicity profile. Using an array of biophysical techniques, we demonstrated the uniqueness of the composite glycine residues in these structural repeats. We used solvent relaxation NMR spectroscopy to investigate the role played by the surrounding water molecules in determining the corresponding aggregation pathway. Notably, the conformational changes induced by Gly³³ and Gly³⁷ mutations result in significantly decreased toxicity in a neuronal cell line. Our results indicate that G³³xxxG³⁷ is the primary motif responsible for Aβ neurotoxicity, hence providing a direct structure–function correlation. Targeting this motif, therefore, can be a promising strategy to prevent neuronal cell death associated with Alzheimer's and other related diseases, such as type II diabetes and Parkinson's.     

Filtering Super-Resolution Scan Conversion of Medical Ultrasound Frames

Wireless Personal Communications - In this paper, we consider a challenging problem of reconstruction of high resolution (HR) B-mode ultrasound (US) image by proposing a novel multi-frame based...     

Exploration of photoreduction ability of reduced graphene oxide–cadmium sulphide hetero-nanostructures and their intensified activities against harmful microbes

Journal of Materials Science - Fabrication of effective photocatalyst using semiconductors and graphene or reduced graphene oxide has been regarded as one of the most promising task to attenuate...     

Analysis of Frequency,Intensity, and Interference of Discomfort in Computerized Numeric Control Machine Operations

The introduction of Computerized Numeric Control (CNC) technology in manufacturing industries revolutionized the production process a few decades back. There are some health and safety problems associated with these machine operations, however. The main objectives of the present work is to study the health and safety issues associated with the CNC machines with respect to control and display, specifically to determine the frequency, intensity of discomfort, and its interference in operating different CNC machines as reported by the workers operating them. The postural discomfort associated with CNC machines was studied, and the frequency, intensity of discomfort, and interference of the level of discomfort with the participants' ability to work were recorded and analyzed. The study revealed that 20.5% of the operators reported discomfort 1 or 2 times, 25.4% experienced discomfort 3 to 4 times in a week, 37.7% had discomfort daily, and 16.4% reported discomfort several times a day. Discomfort was reported in all the body parts involved (lower back, neck, upper back, shoulder, and leg), but the highest discomfort scores were associated with the shoulder and arm region. Workers reporting discomfort several times a day also reported high mean discomfort scores. The study established that the frequency and intensity of the discomfort in all body parts is related to the position of the control panel and display. © 2012 Wiley Periodicals, Inc.     

Identifying and assessing the critical risk factors in an underground rail project in Thailand: a factor analysis approach

Large and complex infrastructure projects involve various risk factors and the successful implementation of such projects depends on effective management of the key risk factors. This paper reviews the literature to identify essential risk variables associated with infrastructure projects. Based on these risk variables, a survey is conducted to isolate and assess the critical risk factors for a mass rapid-transit underground rail project (Chaloem Ratchamongkhon Line), Thailand. Responses obtained within the project organisation are evaluated using principal component analysis to understand the latent structure of the critical risk factors. The variables within the factors are tested to confirm the reliability and validity of the constructs. Finally, nine critical factors with 35 items are extracted after four iterations. Critical risk factors obtained through the factor analysis are assessed to gain better understanding of their importance and impact on project management. The research findings are supported by the perceptions of the senior management within the project organisation, which are also discussed in the paper.     

Improved prediction of simultaneous local and overall buckling of stiffened panels

In this paper, improved expressions for elastic local plate buckling and overall panel buckling of uniaxially compressed T-stiffened panels are developed and validated with 55 ABAQUS eigenvalue buckling analyses of a wide range of typical panel geometries. These two expressions are equated to derive a new expression for the rigidity ratio (EI_x/Db)_CO that uniquely identifies “crossover” panels—those for which local and overall buckling stresses are the same. The new expression for (EI_x/Db)_CO is also validated using the 55 FE models. Earlier work by Chen (Ultimate strength analysis of stiffened panels using a beam-column method. PhD Dissertation, Department of Aerospace and Ocean Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA, 2003) had produced a new step-by-step beam-column method for predicting stiffener-induced compressive collapse of stiffened panels. An alternative approach is to use orthotropic plate theory. As part of the validation of the new beam-column method, ABAQUS elasto-plastic Riks ultimate strength analyses were made for 107 stiffened panels—the 55 crossover panels and 52 others. The beam-column and orthotropic approaches were also used. A surprising result was that the orthotropic approach has a large error for crossover panels whereas the beam-column method does not. Some possible reasons for this are suggested.